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71.
Jean-Baptiste Peyaud Jocelyn Barbarand Andy Carter Maurice Pagel 《International Journal of Earth Sciences》2005,94(3):462-474
The paleogeography during Early Cretaceous of the northern margin of the Ligurian Tethys is poorly constrained because of deformation and erosion during Pyrenean and Alpine orogenic phases. The present-day limit between Lower Cretaceous sediments in the South–East basin, located at the northwestern margin of the Ligurian Tethys, and basement rocks is the consequence of a protracted erosion history. Lower Cretaceous sediments observed today in the basin, even close to the present-day outcropping border, are characteristic of pelagic environments. A larger extent of a Lower Cretaceous cover on the basement must then be considered. This study focuses on the western part of this margin (the Causses basin), in the South of the Massif Central (France), using several thermochronometers and geothermometers to decipher the former extent of the sedimentary cover. Apatite fission track thermochronology on basement rocks surrounding the Causses basin suggests that these rocks cooled from temperatures higher than 110°C during the mid-Cretaceous. Average fluid inclusion homogenisation temperatures between 94°C and 108°C are recorded in calcite veins from outcropping Toarcian and Aalenian shales. In the shales, Tmax values, temperature obtained by Rock–Eval pyrolysis of organic matter, are in agreement with these elevated temperatures. Different explanations for these relatively high temperatures, which cannot be explained by the present-day sedimentary serie in the basin, have been tested using a 1D thermal modelling procedure (Genex). For a 95±10-mW/m2 paleoflux, thick sedimentary deposits (2.5±0.3 km) including 1.3±0.3 km of Lower Cretaceous sediments cover the South of the Massif Central; these formations have been subsequently eroded from mid-Cretaceous time onwards. This study confirms that the South of the Massif Central was a site of marine sedimentation during the Early Cretaceous where a thick sedimentary sequence was once deposited. 相似文献
72.
Wallace S. Broecker Rik Wanninkhof Guy Mathieu Tsung-Hung Peng Scott Stine Steve Robinson Andy Herczeg Minze Stuiver 《Earth and Planetary Science Letters》1988,88(1-2)
Since 1957 the 14C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced14C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO2 exchange rate, and (4) biological enhancement of the CO2 exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity. 相似文献
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74.
Mark E Hodson 《Geochimica et cosmochimica acta》2002,66(5):819-828
A Soxhlet extraction was carried out over a period of 27 d on a column comprising 3 cm of quartz overlain by 4 cm of soil from the B horizon and then 1 cm of soil from the A horizon of a granitic podzol. Major and trace elements were leached from the column and accumulated in a reservoir at the base of the column. Total loss of elements from the soil over the course of the experiment ranged from 0.002 to 1 wt% with major elements and the light and heavy rare earth elements (REE) showing the largest percentage losses. Zirconium (0.002%) and then Al (0.008%) showed the lowest percentage loss. The light REE were leached out of the soil preferentially to the mid REE. All elements showed accumulation, by a factor of 2 to 11, in the quartz layers at the base of the column, particularly in the upper first 1 cm of the quartz. Major elements were leached from the column at a rate of 0.02 to 0.59 μmol h−1 whereas Zr, Nd, Sm, Gd, Dy, Rb, and Sr were leached at the rate of 0.5 to 30 × 10−6 μmol h−1. Concentrations of other REE in the reservoir increased over the duration of the experiment, but they were poorly correlated with time, so leaching rates were not calculated. Normalization of the major element leaching rates to take into account the constant flushing of water through the column, the average annual rainfall in the Allt a’Mharcaidh catchment in Scotland from where the soil was sampled, and the cross-sectional area of the soil in the column, together with the temperature of the soil in the column (70°C) compared with the average annual temperature of the Allt a’Mharcaidh catchment (5.7°C), gave major element release rates from the soil of 0.002 to 0.97 mEq m−2 yr−1 (depending on the choice of Ea, the dissolution activation energy), which are generally less than those measured in the field of 0.1 to 40.9 mEq m−2 yr−1.Calculations showed that despite the redistribution and loss of Zr from the column, assumptions of Zr mobility would have had a negligible effect on calculated element release rates of Na, Ca, Fe, and Mg. However, significant underestimates of the release of K (5%), Ti (57%), Al (5%), and Si (10%) as well as some trace elements (e.g., Nd, 23%; Rb, 54%; Sr, 24%) would have occurred. Concentrations of Ca and Sr leached from the column correlated well (RSQ = 0.93, p < 0.01), supporting the idea of the use of Sr release as a proxy for Ca release in weathering rate calculations. The release rates and percentage loss of REE from the soil varied between elements indicating that REE distribution patterns of rocks and soils may not be preserved in drainage waters. 相似文献
75.
<正> 森林提供许多有价值的生态服务,诸如保护流域和生物多样性以及贮存碳素等,现已引起企业、政府乃至个人越来越多的关注,同时人们也意识到随着森林这些功能的退化甚至丧失所带来的危险和代价。这种退化既能引起洪水、山崩之类的局部灾难,也会导致全球气候变化之类的广泛影响。 相似文献
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78.
The relationship between Cu speciation in solution and mortality and tissue Cu concentrations in Eisenia fetida was investigated. E. fetida were exposed to solutions containing 0.009, 0.049 and 0.125 mg Cu L−1and 0, 0.15, 0.35 and 50 mg EDTA L−1. Mortalities of 100, 60, 50 and 25% were recorded in the 0.125 mg Cu L−1 solutions containing 0, 0.15, 0.35 and 50 mg EDTA L−1, respectively. Similarly tissue body burden decreased with increasing EDTA concentration. Complexation capacity of the solution increased with EDTA concentration. In the 0.125 mg Cu L−1 solution labile Cu concentration decreased with increasing EDTA concentration. These trends are attributed to complexation of free Cu ions with EDTA molecules, and the non-bioavailable nature of the resultant Cu–EDTA complex. 相似文献
79.
Richard J. Bathurst Amin Keshavarz Saman Zarnani W. Andy Take 《Soil Dynamics and Earthquake Engineering》2007,27(4):344-353
A simple displacement-type block model is proposed to compute the compression–load–time response of an idealized seismic buffer placed against a rigid wall and used to attenuate earthquake-induced dynamic loads. The seismic buffer is modelled as a linear elastic material and the soil wedge shear surface by a stress-dependent linear spring. The model is shown to capture the trends observed in four physical reduced-scale model shaking table tests carried out with similar boundary conditions up to a base excitation level of about 0.7g. In most cases, quantitative predictions are in reasonable agreement with physical test results. The model is simple and provides a possible framework for the development of advanced models that can accommodate more complex constitutive laws for the component materials and a wider range of problem geometry. 相似文献
80.